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Sodium and Chloride
In Drinking Water
The compound known as "salt" consists of the elements sodium and chloride.
Many people use the word salt when they are actually referring to sodium.
Every water supply contains some sodium and chloride. When salt dissolves
in water it changes its form from a solid to an "ion." An atom or molecule
that has dissolved in water is called an "ion". Salt readily dissolves
in water. A chemist would use the following abbreviations when describing
salt dissolved in water: sodium (Na+) and chloride (Cl-).
Occurrence of Sodium and Chloride
Typical background levels of Na+ and Cl- for pristine locations in
New Hampshire are generally less than 15 milligrams per liter (mg/L) and
30 mg/L respectively. A milligram per liter is the same as saying a part
per million parts (ppm). In the immediate seacoast area, elevated levels
of Na+ and Cl- occur naturally due to the proximity to sea water. Seacoast
area concentrations typically range up to 100 mg/L and 150 mg/L respectively.
Normally the chloride concentration of well water exceeds the sodium:
often by approximately 50 percent. This is typically caused by the relative
atomic weights of each, and the tendency of the soil to retard or chemically
combine more with sodium than with chloride. Any judgment relative to a
water's salt concentration should be made only after reviewing the results
of a few samples that have been taken at different times of the year.
Substantially higher levels of Na+ and Cl- tend to imply contamination
by activities of man including road salt storage, use of road salts, discharges
from water softeners, human or animal waste disposal, leachate from landfills,
and other activities.
DES Policy on Deicing Salts
Safe driving conditions on our highways are important to residents
and visitors alike. The application of deicing salts is a very important
component of maintaining road safety. The environmental impact of deicing
salts can be minimized by use of best management practice including:
Covering salt piles;
Paved areas for loading salt trucks; and
Modern, truck-mounted, application equipment that is controllable from
the operator's cab.
For more information concerning road salt management and the effect of
road salt on surface water quality, please see DES fact sheet WD-WMB-4.
Health Implications
(The following information concerning health Implications has been
provided by the Bureau of Health Risk Assessment of the Department of Public
Health Services. They can be reached at 271-4608.)
At present there are no health standards for Na+ or Cl- in drinking
water. In the mid-1980s EPA had listed sodium in a group of contaminants,
called the Drinking Water Priority List, for which official maximum contaminant
levels (MCLs) would be developed. MCLs are health-based standards that
must be met by public water systems. A subsequent review of scientific
evidence by EPA showed that the vast amount of sodium ingestion was from
food rather than drinking water, and that the linkage between sodium and
hypertension (high blood pressure) was still not well documented. Consequently,
in 1988, EPA removed sodium from that list of drinking water contaminants
proposed to be formally regulated by the Safe Drinking Water Act.
On March 2, 1998 EPA reissued the list of contaminants for which MCLs
may be developed. This list is now called the Drinking Water Contaminant
Candidate List (DWCCL). This current list includes sodium.
Many brief EPA discussions concerning sodium in drinking water have
appeared in the Federal Register over the last 15 years as noted below.
The last three of these documents are included at the end of this fact
sheet.
Wednesday, November 13, 1985, page 46980;
Wednesday, July 8, 1987, page 25723;
Friday, January 22, 1988, page 1894;
Monday, January 14, 1991, page 1471;
Monday, October 6, 1997, page 52211; and
Monday, March 2, 1998, page 10283.
When considering the health importance of Na+ and Cl-, EPA assumed that
water users consume two liters of water per day and that 10 percent or
less of a person's daily sodium intake comes from drinking water. The rest
of an average person's sodium intake is usually from food. Persons on a
sodium restricted diet should evaluate all possible sources of sodium when
attempting to reduce overall intake. It is often much easier and less expensive
to make a dietary change than to excessively purify drinking water.
EPA has recommended that sodium levels not exceed 20 mg/L for those
persons on a physician-prescribed "no salt diet". This is the same
level recommended by the American Heart Association. This is a very stringent
level. For comparison purposes, regular milk has a sodium concentration
of approximately 500 mg/L. The sodium levels of certain other major foods
are listed below.
| Food Product |
Sodium Concentration |
| Antacid |
500 mg/L |
| Tomato sauce, cup |
1,500 " |
| Ham, 3oz` |
1,100 " |
| Bacon, 4 slices |
550 " |
| Cottage cheese |
450 " |
| White wine, 4oz |
20 " |
| Club soda, 8 oz |
40 " |
Na+ and Cl - are generally not major contaminants in the water served
by community public water systems in New Hampshire. Such systems typically
have concentrations of Na+ and Cl- that are less than 75 mg/L each in almost
all cases. Your local public water system is required to inform its customers
annually of all water quality factors including Na+ and Cl-. There are
no known health concerns with chloride.
Secondary (Aesthetic) Drinking Water Standards
Both Na+ and Cl- cause a taste in water. EPA has identified a concentration
of over 250 mg/L of either Na+ & Cl- as a concentration which can be
expected to impart a "salt" taste to drinking water. Typically chloride
has the stronger taste response. This level is based on aesthetic concerns
and is only advisory in the EPA Safe Drinking Water Act program.
Control of Sodium and Chloride
Normally the best method to control Na+ and Cl- in drinking water is
to better manage those activities that add salt near the recharge area
of the water supply source(s). The following are the most common sources
of salt in water supplies.
Application of road deicing salts. Road salt runoff
can contaminant groundwater. Limiting the application of salt in the vicinity
of a well, rerouting runoff, and installing clay-lined drainage swales
along the roadside may all reduce the Na+ and Cl- concentrations in adjacent
wells. If a well is contaminated by de-icing salts and the origin is suspected
to be from a state highway, the New Hampshire Department of Transportation,
Bureau of Highway Maintenance, may help correct the situation. Please call
them at 603-271-2693 for more information.
Water softeners add sodium to drinking water in two ways. Directly
during the hardness removal process, and indirectly by the discharge of
waste brine (salt dissolved in water) into subsurface disposal systems.
The amount of salt added by a water softener can be substantial if a water's
hardness is high. The volume of waste brine generated in the regeneration
cycle can be reduced by using water meters or ion probes to trigger regeneration.
This is called demand regeneration. See fact sheet WD-WSEB-3-6
concerning hardness in drinking water.
Other Sources. Many water treatment chemicals have sodium as
a basic ingredient. These chemicals often perform a valued treatment function.
However, they do raise the sodium level in water proportional to the amount
applied. Near the coast, some sodium and chloride may be due to sea water
from either storm spray or underground intrusion.
Sanitary Significance of Sodium and Chloride
Na+ and Cl- are also present in human wastewater. Finding the source
of elevated Na+ and Cl- is important since Na+ and Cl- may indicate the
nearby disposal of human wastewater or solid fecal waste. The presence
of elevated Na+ and Cl- must initially be considered as an indication of
increased risk of more serious bacterial or chemical pollution until a
more detailed analysis identifies the origin of the Na+/ Cl-.
Treatment to Remove Sodium or Chloride
Sodium and chloride are costly to remove from water. Effective treatment
types include:
| Treatment Type |
Drawbacks |
| Reverse osmosis |
May not be practical for high volume need due to the cold water "reject"
rate |
| Distillation |
Very costly to operate |
| De-ionization (Ion exchange) |
Practical |
Where treatment is going to be installed, the size of the device can
range from an under-the-sink system to full house treatment. If only pure
drinking
water is the goal, then an under-the-sink system will suffice.
The presence of elevated levels of sodium and chloride somewhat increases
the water's ionic conductance and thus increases the potential for corrosive
damage to plumbing fixtures. To reduce this damage totally, the treatment
system would need to be installed to service the entire home. Bottled water
is also an option to address the health concerns (posed by leached lead
and copper caused by corrosive water) in the interim period, while a long-term
solution is being investigated.
For further information concerning the layout of a water treatment system
and its purchase, the DES suggests reviewing the fact sheet entitled, "Considerations
when Purchasing a Water Treatment System," WD-WSEB-2-5.
Vegetation Damage
Highway de-icing salt application can impact vegetation. Windblown
salt spray can be as much a concern as salt laden water runoff. In general,
damage lessens with greater distance from the road, lower salt application
rates and the species of tree. Salt tolerant species include Norway maples,
horse chestnut, white ash, Colorado spruce, white popular, and golden weeping
willow to name some. For more details concerning vegetation damage please
call UNH Cooperative Extension at 862-3200.
FOR MORE INFORMATION
If you have additional questions, please call the DES's Water Supply
Engineering Bureau at (603) 271-3139. We would appreciate your comments
concerning this fact sheet and the treatment of Na+ and/or Cl-. For an
overall listing of water supply related fact sheets, please request WD-WSEB-15-2.
Drinking water fact sheets are available through the DES web site at: http://www.des.state.nh.us/ws.htm
then select: publications, fact sheets, water division, water supply.
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